Electronic Resource

MWW-type titanosilicate: synthesis, structural modification and catalytic applications to green oxidations

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This book provides a comprehensive review of a new generation of selective oxidation titanosilicate catalysts with the MWW topology (Ti-MWW) based on the research achievements of the past 12 years. It gives an overview of the synthesis, structure modification and catalytic properties of Ti-MWW. Ti-MWW can readily be prepared by means of direct hydrothermal synthesis with crystallization-supporting agents, using dual-structure-directing agents and a dry-gel conversion technique. It also can be post-synthesized through unique reversible structure transformation and liquid-phase isomorphous substitution. The structural conversion of Ti-MWW into the materials usable for processing large molecules is summarized. Taking advantage of the structure diversity of the lamellar precursor of Ti-MWW, it can be fully or partially delaminated, and undergo interlayer silylation to obtain a novel structure with larger porosity. In the selective oxidation (alkene epoxidation and ketone/aldehyde ammoximation) with hydrogen peroxide or organic peroxide as an oxidant, the unique catalytic properties of Ti-MWW are described in comparison to conventional titanosilicates such as TS-1 and Ti-Beta.

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Ketersediaan

Informasi Detail

Judul Seri

SpringerBriefs in Molecular Science

No. Panggil

E334

Penerbit

Berlin : Springer Berlin., 2013

Deskripsi Fisik

VIII, 125 Hlm.

Bahasa

English

ISBN/ISSN

9783642391156

Klasifikasi

NONE

Tipe Isi

text

Tipe Media

computer

Tipe Pembawa

online resource

Edisi

1

Subjek

Kimia Fisik
Kimia Lingkungan
Katalisis

Info Detail Spesifik

-

Pernyataan Tanggungjawab

Peng Wu, Hao Xu, Le Xu, Yueming Liu, Mingyuan He

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